RuCl(p-cymene)[(R,R)-Ts-DPEN]
Synonym: [N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
Molecular weight : 636.21 g/mol
CAS-No. : 192139-92-7
Formula: C31H35ClN2O2RuS
Form: orange to brown powder
Melting point/range: 215 °C
Storage:
Keep container tightly closed in a dry and well-ventilated place.
Recommended storage temperature 2 - 8 °C
Air and moisture sensitive. Handle and store under inert gas.
Precautions for safe handling:
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:
• Quinolines
• N-Alkyl ketimines
• Antitumor and antiproliferative derivatives of natural products isolated from bacteria
• Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation
Catalyst with improved performance modified via microenvironment engineering of nanocages
General description
RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.
